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WEEK 6
TOPIC: NITROGEN
CONTENTS:
- General properties of nitrogen–group va elements, laboratory and industrial preparation of nitrogen,
- Properties and uses of nitrogen
- Compound of nitrogen – ammonia- laboratory and industrial preparation
- Properties and uses, test for ammonia, fountain experiment
PERIOD 1: GENERAL PROPERTIES OF NITROGEN – GROUP V ELEMENTS
Nitrogen and other group VA elements are non-metals and show two common valences of 3 and 5. They are electron acceptors and both form several acidic oxides. They also form similar hydrides and chloride e.g., Nitrogen and phosphorus form N2O3 and P4O6, N2O5 and P4O10, NH3, PH3, NCl3 and PCl3
Properties of VA elements
Property
|
Nitrogen
N |
Phosphorous
P |
Arsenic
As |
Antimony
Sb |
Bismuth
Bi |
Atomic number | 7 | 15 | 33 | 51 | 83 |
Outer electron configuration | 2s22p6 | 3s23p3 | 3d104s2 4p3 | 4d104s25p3 | 4f15d106s26p3 |
Atomic mass | 14.0067 | 30.9738 | 74.9216 | 121.75 | 208.980 |
Boiling point
Melting point |
-196
-210 |
280w
44w 2.34r |
610sr
817pgr 5.73gr |
1380
630gr 6.7gr |
1560
271 9.8 |
Density(gcm-3) | 0.81 | 1.82w |
W = white, gr = grey, p = 28 atmospheres, r = red, s = sublimes
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